Synthesis, Characterisation and X-Ray Structure of Ferrocenyl N-Heterocyclic Carbene Complexes of Rhodium(I)

Onyancha, Douglas; Cedric, McCleland; Gerber, Thomas

dc.contributor.author	Onyancha, Douglas
dc.contributor.author	Cedric, McCleland
dc.contributor.author	Gerber, Thomas
dc.date.accessioned	2016-02-25T12:02:04Z
dc.date.available	2016-02-25T12:02:04Z
dc.date.issued	2016
dc.identifier.issn	2150-3494
dc.identifier.uri	http://41.89.227.156:8080/xmlui/handle/123456789/442
dc.description.abstract	The synthesis, spectroscopic and structural characterization of Rh(I) ferrocenyl N-heterocyclic carbene complexes are described. The in situ deprotonation of the imidazolium salts with KOBut and subsequent complexation to rhodium(I) proved to be an efficient route for their synthesis yielding good too excellent yields. The X-ray crystal structure of bromo(η4-1,5-cyclooctadiene)(1-ferrocenyl-3-propyl-1H-imidazol-2-ylidene)rhodium(I) was obtained and reveals substitution disorder of a bromine and chlorine atom on Rh(1) in the ratio of 0.96/0.04.	en_US
dc.language.iso	en	en_US
dc.publisher	Chemical Sciences Journal	en_US
dc.relation.ispartofseries	Volume 7;Issue 1
dc.subject	Ferrocenylimidazolium salts; Ferrocenyl N-heterocyclic carbene rhodium(I); X-Ray crystal structure	en_US
dc.title	Synthesis, Characterisation and X-Ray Structure of Ferrocenyl N-Heterocyclic Carbene Complexes of Rhodium(I)	en_US
dc.type	Article	en_US